By Roy,G D Ed

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Careful planning of research, together with cooperative research efforts among several investigators, resulted in better understanding of the practical issues and faster transition of the knowledge to the design community. A rapid advance in supercomputing and massively parallel processing has brought forth computational capabilities hitherto unheard of. Computational combustion dynamics has paved a new route to perform numerical experiments and to guide experimentalists to design more optimal test configurations [4].

The numerical model and the software created make it possible to determine the combustion and ignition characteristics of polydispersed mixtures. The model has been validated with experiments. In an experimental effort, measurements of turbulent flame speeds in gaseous reactants in a classic cylindrical Taylor–Couette burner were made by Ralph Aldredge at the University of California at Davis (Chapter 15). The study established sensitivity of the turbulent flame speed to turbulence intensity, and provided some influence of flame front wrinkling on flame propagation.

After hours, or even days, the 1 H NMR spectra showed only completely unreacted starting material, in each case. No reaction occurred even upon heating at 40 ◦ C. To test for the conversion of catalyst activity with time, norbormene was added to one of the basketene reaction mixtures after 2 days and it was readily polymerized, while the basketene remained intact. Work continues on finding conditions for successful polymerization. (b) Polymerization attempts in the presence of the molybdenum catalyst (compound 23) Procedure Reactions were carried out under argon, in sealed NMR tubes, at room temperature or with mild heating.

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